แจ้งเอกสารไม่ครบถ้วน, ไม่ตรงกับชื่อเรื่อง หรือมีข้อผิดพลาดเกี่ยวกับเอกสาร ติดต่อที่นี่ ==>
หากไม่มีอีเมลผู้รับให้กรอก thailis-noc@uni.net.th
หากไม่มีอีเมลผู้รับให้กรอก thailis-noc@uni.net.th
Tanabadee Boonmalert. Synthesis of epoxypolyphenylene oxide blend compatibilized by triallylisocyanurate. Master's Degree(Chemical Engineering). Kasetsart University. Office of the University Library. : Kasetsart University, 2020.
Synthesis of epoxypolyphenylene oxide blend compatibilized by triallylisocyanurate
Name: Tanabadee Boonmalert
Classification :.LCCS: TP1180.E6
LCSH:
Epoxy resins
LCSH:
Polyphenylene oxide
LCSH:
Compatibilizers
Abstract:
Epoxy resins (EP) are widely used in electronic devices due to its low price, good processability, high thermal stability and good solvent resistance. Due to the crosslink nature EPs exhibit some drawbacks such as low crack resistance and high dielectric constant. To overcome this problem, EP can be blended with thermoplastic polymer such as poly (phenylene oxide) (PPO). PPO is a hightemperature thermoplastic polymer with good mechanical properties and extremely low dielectric constant. However, the poor compatibility of PPO and EP leads to phase separation which can limit their processability and final product properties. In this research, triallylisocyanurate (TAIC) was used as a compatibilizer in polymer blend between EP and PPO. Different ratios of EP/PPO/TAIC were varied to obtain suitable formulation with desired mechanical and thermal properties. Silica particles (30-60 phr) were also incorporated into the blends for enhanced Tg and modulus. It was found that addition of TAIC provided good compatibility between EP and PPO matrix allowing their molecular chains to come close to each other. The three allyl groups in the TAIC structure can readily react with PPO and EP molecules or selfpolymerize to form a network. Hence, higher Tg and modulus were observed with TAIC addition. However, only appropriate mixing ratios (50/50/25, 50/25/50, and 50/25/25) of EP/PPO/TAIC were found to exhibit superior properties. Excessive TAIC content can lead to reduction in Tg since unreacted TAIC can cause plasticizing effect. In addition, silica particles can significantly improve thermal and mechanical properties of EP/PPO/TAIC systems. The maximum Tg value and storage modulus were reported at silica content up to 40 phr. At higher content, agglomerations were observed and could be responsible for a decrease in Tg and modulus.
Kasetsart University. Office of the University Library
Address:
Bangkok
Email:
tdckulib@ku.ac.th
Name: Peerapan Dittanet
Role:
Thesis Advisor
Created:
2020
Modified:
2025-07-22
Issued:
2025-07-22
วิทยานิพนธ์/Thesis
application/pdf
URL: https://www.lib.ku.ac.th/KUthesis/2563/tanabadee-boo-all.pdf
CallNumber:
TP1180.E6 .T36
eng
DegreeName: Master of Engineering
Level: Master's Degree
Descipline: Chemical Engineering
Grantor: Kasetsart University
©copyrights Kasetsart University
RightsAccess:
ใช้เวลา
0.029194 วินาที
Tanabadee Boonmalert
| Title | Contributor | Type |
|---|---|---|
| Extraction of cellulose nanocrystals and nanofibers from rubber leaves and their impacts on natural rubber properties
มหาวิทยาลัยเทคโนโลยีพระจอมเกล้าพระนครเหนือ Wanasorn Sompol.;Napassorn Chanka.;Tanabadee Boonmalert.;Surapich Loykulnant.;Paweena Prapainainar.;Anusorn Seubsai.;Peerapan Dittanet. | บทความ/Article | |
| Synthesis of epoxypolyphenylene oxide blend compatibilized by triallylisocyanurate
มหาวิทยาลัยเกษตรศาสตร์ Tanabadee Boonmalert | Peerapan Dittanet | วิทยานิพนธ์/Thesis |
Peerapan Dittanet