Aunyamanee Plucksacholatarn. A Theoretical investigation on electronic transitions and phosphorescent properties of tetradentate Pt(II) complex PhOLEDS. Master's Degree(Chemistry). Kasetsart University. Office of the University Library. : Kasetsart University, 2017.
A Theoretical investigation on electronic transitions and phosphorescent properties of tetradentate Pt(II) complex PhOLEDS
Abstract:
One problem that many research groups was found is about blue OLEDs due to lower efficiency than red and green OLEDs. Tetradentate platinum(II) complexes are interesting for OLEDs owing to generating light from both singlet and triplet excitons, so they can approach 100% quantum yield and generate phosphorescence. There are two families of blue tetradentate platinum (II) complexes that are passionate for studying. The first one is the family of tetradentate platinum (II) complexes bridging with carbazole unit that can generate high quantum efficiency about 70%. The second one is the family of tetradentate platinum(II) complexes containing dianionic bis(phenolate-NHC) ligands which can generate lower quantum efficiency less than 20% by Kai et al. (2011) reporting. These are the interesting topic that why two type families of blue cyclometalated tetradentate platinum (II) OLEDs have difference of phosphorescent efficiency by investigating with three complexes that can link between two structural aforementioned groups for further understanding. So, in this work we focus on a theoretical investigation on relation of structural molecules and phosphorescent properties by considering phosphorescent properties, electronic transitions, structural distortions, the difference of energy level, d-orbital splitting and so on with DFT method mixed LANL2DZ and 6-31G(d) basis set.
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