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Ratanon Chotima. Effect of additional phosphine in n-butanol production catalyzed by Fe(II)-N-heterocyclic carbene complexes. (). King Mongkut's University of Technology North Bangkok. Central Library. : , 2018.
Effect of additional phosphine in n-butanol production catalyzed by Fe(II)-N-heterocyclic carbene complexes
Name: Nattapong Siengdang
Organization :
Chulalongkorn University. Faculty of Science
Name: Watsapon Yimkaew
Organization :
Chulalongkorn University. Faculty of Science
Name: Bussaba Boonseng
Organization :
Naresuan University. Faculty of Science
Name: Ratanon Chotima
Organization :
Naresuan University. Faculty of Science
Email :
ratanonc@nu.ac.th
keyword:
n-Butanol
Abstract:
n-Butanol is considered as one of the alternative biofuels which can be synthesized
via Guerbets reaction using a metal complex as a homogeneous catalyst. A series of
complexes between Fe(II) and N-heterocyclic carbenes, 1,3-bis(2,4,6-trimethylphenyl)-4,5-
dihydroimidazol-2-ylidene (SIMes), 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes)
and 1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene (SIPr), was synthesized in order to use
as catalysts in the production of n-butanol from ethanol. Triphenylphosphine was also
introduced to the complexes which expected to enhance the catalytic efficiency. The
complexes were characterized by nuclear magnetic resonance spectroscopy (1H-NMR and
31P{1H}-NMR). The spectrum revealed that there were both N-heterocyclic carbenes and
triphenylphosphine in the synthesized complexes, but the intrinsic structure of the complexes
could not be confirmed. The amount of products was increased when lengthened the reaction
time. The catalytic production of n-butanol from ethanol was performed at 80 ˚C and 150 ˚C,
and monitored by gas chromatography (GC). The chromatogram of the catalytic reaction
showed only trace amount of n-butanol production.
King Mongkut's University of Technology North Bangkok. Central Library
Address:
BANGKOK
Email:
library@kmutnb.ac.th
Created:
2018
Modified:
2562-07-04
Issued:
2019-07-04
บทความ/Article
application/pdf
BibliograpyCitation :
In Prince of Songkla University Faculty of Science. Pure and Applied Chemistry International Conference (PACCON 2018) (p.IN31-IN35). Songkla : Prince of Songkla University
eng
©copyrights King Mongkut's University of Technology North Bangkok
RightsAccess:
ใช้เวลา
0.035958 วินาที
Nattapong Siengdang
| Title | Contributor | Type |
|---|---|---|
| Effect of additional phosphine in n-butanol production catalyzed by Fe(II)-N-heterocyclic carbene complexes
มหาวิทยาลัยเทคโนโลยีพระจอมเกล้าพระนครเหนือ Nattapong Siengdang;Watsapon Yimkaew;Bussaba Boonseng;Ratanon Chotima | บทความ/Article |
Watsapon Yimkaew
| Title | Contributor | Type |
|---|---|---|
| Effect of additional phosphine in n-butanol production catalyzed by Fe(II)-N-heterocyclic carbene complexes
มหาวิทยาลัยเทคโนโลยีพระจอมเกล้าพระนครเหนือ Nattapong Siengdang;Watsapon Yimkaew;Bussaba Boonseng;Ratanon Chotima | บทความ/Article | |
| Development of copper(I) and iron(II) N-heterocyclic carbene complexes catalyzed the synthesis of n-butanol from ethanol
มหาวิทยาลัยเทคโนโลยีพระจอมเกล้าพระนครเหนือ Watsapon Yimkaew;Panukorn Sombut;Bussaba Boonseng;Ratanon Chotima | บทความ/Article |
Bussaba Boonseng
Ratanon Chotima
| Title | Contributor | Type |
|---|---|---|
| Synthesis, characterization and application of complex between 3-(2-Thiazolylazo)-2,6-diaminopyridine and ruthenium (III)
มหาวิทยาลัยเกษตรศาสตร์ Ratanon Chotima, 1983- | Apisit Songsasen | วิทยานิพนธ์/Thesis |
| Synthesis, characterization and anticancer studies of acesulfame mixed with triphenylphosphine silver(I) complexes
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| Effect of additional phosphine in n-butanol production catalyzed by Fe(II)-N-heterocyclic carbene complexes
มหาวิทยาลัยเทคโนโลยีพระจอมเกล้าพระนครเหนือ Nattapong Siengdang;Watsapon Yimkaew;Bussaba Boonseng;Ratanon Chotima | บทความ/Article | |
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| Development of copper(I) and iron(II) N-heterocyclic carbene complexes catalyzed the synthesis of n-butanol from ethanol
มหาวิทยาลัยเทคโนโลยีพระจอมเกล้าพระนครเหนือ Watsapon Yimkaew;Panukorn Sombut;Bussaba Boonseng;Ratanon Chotima | บทความ/Article |