Thayukorn Prabamroong. Surface Ozone and Its Control Strategies for Chon Buri City, Thailand. Doctoral Degree(Environmental Technology). King Mongkut's University of Technology Thonburi. KMUTT Library. : King Mongkut's University of Technology Thonburi, 2011.
Surface Ozone and Its Control Strategies for Chon Buri City, Thailand
Abstract:
This work studies O3 pollution for Chon Buri City in the eastern region of Thailand,
where O3 has become an increased and serious concern in the last decade. It includes
emission estimation and photochemical box modeling in support of investigating the
underlying nature of O3 formation over the city and the roles of precursors emitted from
sources. The year 2006 was considered and two single-day episodes (Jan. 29 and Feb. 14)
were chosen for simulations. It was found that, in the city, the industrial sector is the
largest emissions contributor for every O3 precursor (i.e., NOx, non-methane volatile
organic compounds or NMVOC, and CO), followed by on-road mobile group. Fugitive
NMVOC is relatively large, emitted mainly from oil refineries and tank farms. Simulated
results acceptably agree with observations for daily maximum O3 level in both episodes
and evidently indicate the VOC-sensitive regime for O3 formation. This regime is also
substantiated by morning NMVOC/NOx ratios observed in the city. The corresponding O3
isopleth diagrams suggest NMVOC control alone to lower elevated O3. In seeking a
potential O3 control strategy for the city, a combination of brute-force sensitivity tests, an
experimental design, statistical modeling, and cost optimization was employed. A number
of emission subgroups were found to significantly contribute to O3 formation, based on the
Feb. 14 episode, e.g., oil refinery (fugitive), tank farm (fugitive), passenger car (gasoline),
and motorcycle (gasoline). But the cost-effective strategy suggests control only on the first
two subgroups to meet the standard. The cost of implementing the strategy was estimated
and found to be small (only 0.2%) compared to the gross provincial product generated by
the entire province where the city is located within. These findings could be useful as a
needed guideline to support O3 management for the city.
King Mongkut's University of Technology Thonburi. KMUTT Library