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Supaporn Sathalalai. Iodine catalyzed fridel-crafts alkylation of lelctron-rich arenes with aldehydes: efficient synthesis of triarylmethanes and diarylalkanes.. Master's Degree(Chemistry). Burapha University. Library. : Burapha University, 2010.
Iodine catalyzed fridel-crafts alkylation of lelctron-rich arenes with aldehydes: efficient synthesis of triarylmethanes and diarylalkanes.
Name: Supaporn Sathalalai
keyword:
triarylmethanes
;
iodine
Abstract:
Molecular iodine was discovered highly effective as catalyst for the Friendel-Crafts alkylation of electron-rich aromatic or heteroaromatic compounds with a wide varity of aldchydes in toluene at ambient temperature under 'open flask' and mild conditions. In the presence of 10 mol% of iodine, electron-rich aromatic or heteroaromatic compounds reacted with aromatic aldehydes regioselectively leading to the formation of the corresponding triarylmethane or diheteroarylarylmethane derivatives with moderate to excellent yields. On the other hand, series of diarylalkane or diheteroarylalkane derivatives was smoothly synthesized by reaction with aliphatic aldehydes. Moreover, the utility and applicability of this method for the synthesis of three bioactive triarylmethanes i.e. 4,4'-dihydroxytriphenylmethane, 4-chlorophenyl bis (4-hydroxyphenyl) methane and 1,1'-(((4-chlorophenyl) methylene)-dinaphthalen)-2-ol varying the aldehyde and arene motifs were accomplished. In each case, exclusive triarylmethanes selectively was observed and no by product was formed.
Burapha University. Library
Address:
Chonburi
Email:
buulibrary@buu.ac.th
Name: Jaray Jaratjaroonphong
Role:
Principal advisor
Created:
2010
Modified:
2021-12-25
Issued:
2010-06-03
วิทยานิพนธ์/Thesis
application/pdf
eng
DegreeName: Master of Science
Level: Master's Degree
Descipline: Chemistry
Grantor: Burapha University
©copyrights Burapha University
RightsAccess:
ใช้เวลา
0.038159 วินาที
Supaporn Sathalalai
| Title | Contributor | Type |
|---|---|---|
| Iodine catalyzed fridel-crafts alkylation of lelctron-rich arenes with aldehydes: efficient synthesis of triarylmethanes and diarylalkanes.
มหาวิทยาลัยบูรพา Supaporn Sathalalai | Jaray Jaratjaroonphong | วิทยานิพนธ์/Thesis |
Jaray Jaratjaroonphong