Valerio D'Elia. Conversion of CO2 to cyclic carbonates catalyzed by lanthanide salen complexes. (). King Mongkut's University of Technology North Bangkok. Central Library. : , 2018.
Conversion of CO2 to cyclic carbonates catalyzed by lanthanide salen complexes
Abstract:
Salen ligands have been widely applied in coordination chemistry of transition metals
because of their excellent advantages such as ease of preparation, low cost and high tunability
of the steric and electronic effects by modifications of the organic scaffolds. In
organolanthanide chemistry, lanthanide salen complexes are considered as efficient catalysts
able to promote several chemical transformations, however, they have not yet been employed
for the conversion of CO2 to value added products. In this work, scandium and yttrium salen
complexes were synthesized and used as homogeneous catalysts in the synthesis of valueadded
cyclic carbonate products by the coupling reaction of CO2 and epoxides. This work
shows the potential of lanthanide salen complexes to catalyze the conversion of CO2 into
cyclic carbonates under mild reaction conditions and with a low catalyst loading.
King Mongkut's University of Technology North Bangkok. Central Library
Address:
BANGKOK
Email:
library@kmutnb.ac.th
Created:
2018
Modified:
2562-07-09
Issued:
2019-07-09
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BibliograpyCitation :
In Prince of Songkla University Faculty of Science. Pure and Applied Chemistry International Conference (PACCON 2018) (p.MN163-MN168). Songkla : Prince of Songkla University