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Valerio D'Elia. Preparation of silica supported zirconium-based heterogeneous catalysts by surface organometallic chemistry strategy for the conversion of CO2 to cyclic carbonates under mild conditions. (). King Mongkut's University of Technology North Bangkok. Central Library. : , 2018.
Preparation of silica supported zirconium-based heterogeneous catalysts by surface organometallic chemistry strategy for the conversion of CO2 to cyclic carbonates under mild conditions
Name: Ounjit Sodpiban
Organization :
Vidyasirimedhi Institute. School of Molecular Science and Engineering
Name: Silvano Del Gobbo
Organization :
Vidyasirimedhi Institute. School of Molecular Science and Engineering
Name: Valerio D'Elia
Organization :
Vidyasirimedhi Institute. School of Molecular Science and Engineering
Email :
Valerio.delia@vistec.ac.th
keyword:
Cyclic carbonates
LCSH:
Organometallic chemistry
LCSH:
Carbon dioxide
-- Analysis
LCSH:
Heterogeneous catalysis
Abstract:
Surface organometallic chemistry (SOMC) is a powerful approach to prepare welldefined
catalytically active sites on the support surface. In this work, organo-zirconium
compounds were prepared and grafted on silica by a facile method. Several materials
differing by the podality of the resulting complexes and by the zirconium surface density with
zirconium-loading between 0.21 and 0.52%wt on silica which has specific surface area 200
m2g-1 were produced. These materials were applied as reusable heterogeneous catalysts to the
conversion of CO2 to cyclic organic carbonates displaying high activity and selectivity under
mild conditions. The catalysts could be reused several times and the correlation between
zirconium-leaching and catalytic activity was carefully investigated. This readily available
family of catalysts constitutes an excellent candidate for application using impure CO2 as a
feedstock.
King Mongkut's University of Technology North Bangkok. Central Library
Address:
BANGKOK
Email:
library@kmutnb.ac.th
Created:
2018
Modified:
2562-07-09
Issued:
2019-07-09
บทความ/Article
application/pdf
BibliograpyCitation :
In Prince of Songkla University Faculty of Science. Pure and Applied Chemistry International Conference (PACCON 2018) (p.MN152-MN157). Songkla : Prince of Songkla University
eng
©copyrights King Mongkut's University of Technology North Bangkok
RightsAccess:
ใช้เวลา
0.038541 วินาที
Ounjit Sodpiban
| Title | Contributor | Type |
|---|---|---|
| Preparation of silica supported zirconium-based heterogeneous catalysts by surface organometallic chemistry strategy for the conversion of CO2 to cyclic carbonates under mild conditions
มหาวิทยาลัยเทคโนโลยีพระจอมเกล้าพระนครเหนือ Ounjit Sodpiban;Silvano Del Gobbo;Valerio D\'Elia | บทความ/Article |
Silvano Del Gobbo
| Title | Contributor | Type |
|---|---|---|
| Preparation of silica supported zirconium-based heterogeneous catalysts by surface organometallic chemistry strategy for the conversion of CO2 to cyclic carbonates under mild conditions
มหาวิทยาลัยเทคโนโลยีพระจอมเกล้าพระนครเหนือ Ounjit Sodpiban;Silvano Del Gobbo;Valerio D\'Elia | บทความ/Article |
Valerio D'Elia
| Title | Contributor | Type |
|---|